This is an interim version of our Electronic Legal Deposit Catalogue-eJournals and eBooks while we continue to recover from a cyber-attack.
Fractional transfer of a free unpaired electron to overcome energy barriers in the formation of Fe4+ from Fe3+ during the core contraction of macrocycles: implication for heme distortion1. Issue 10 (14th March 2015)
Record Type:
Journal Article
Title:
Fractional transfer of a free unpaired electron to overcome energy barriers in the formation of Fe4+ from Fe3+ during the core contraction of macrocycles: implication for heme distortion1. Issue 10 (14th March 2015)
Main Title:
Fractional transfer of a free unpaired electron to overcome energy barriers in the formation of Fe4+ from Fe3+ during the core contraction of macrocycles: implication for heme distortion1
<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj40zvktd" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />The free unpaired electron in Fe<sup>3+</sup> ions cannot be directly removed, and needs a transfer pathway with at least four steps to overcome the high energy barriers to form Fe<sup>4+</sup> ions.</p> </abstract>