Novel electrochemi-/photo-luminescence of Ag3Cu5 heterometallic alkynyl clusters1. Issue 9 (7th March 2015)

• Record Type: Journal Article
• Authors: Jiang, Yi; Guo, Wen-Jing; Kong, De-Xian; Wang, Yong-Tao; Wang, Jin-Yun; Wei, Qiao-Hua
• Is Part Of: Dalton transactions. Volume 44:Issue 9(2015)
• Page Start: 3941
• Page End: 3944
• Publication Date: 2015-03-07
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c4dt03369h
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj40w759z" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Two windmill-like Ag₃Cu₅ alkynyl clusters were synthesized and characterized. They display novel PL and ECL properties, which could be modified by changing the substituent on the alkynyl ligands. According to the study of EC, ECL behaviours and ECL emission spectra of the Ag₃Cu₅ clusters, a possible ECL mechanism was proposed.</p> </abstract>