Modulation of electronic and redox properties in phenolate-rich cobalt(iii) complexes and their implications for catalytic proton reduction1. Issue 7 (21st February 2015)

• Record Type: Journal Article
• Authors: Basu, Debashis; Allard, Marco M.; Xavier, Fernando R.; Heeg, Mary Jane; Schlegel, H. Bernhard; Verani, Claudio N.
• Is Part Of: Dalton transactions. Volume 44:Issue 7(2015)
• Page Start: 3454
• Page End: 3466
• Publication Date: 2015-02-21
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c4dt03337j
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj40xw308" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />The redox, spectroscopic and catalytic activity of a series of cobalt complexes with phenolate-rich environments was investigated. The complex [Co^III(L^Cl)MeOH] shows considerable proton reduction in MeCN:HOAc with TON = 10.8.</p> </abstract>