Decomposition of fluorophosphoryl diazide: a joint experimental and theoretical study1. Issue 9 (7th March 2015)

• Record Type: Journal Article
• Authors: Li, Dingqing; Li, Hongmin; Zhu, Bifeng; Zeng, Xiaoqing; Willner, Helge; Beckers, Helmut; Neuhaus, Patrik; Grote, Dirk; Sander, Wolfram
• Is Part Of: Physical chemistry chemical physics. Volume 17:Issue 9(2015)
• Page Start: 6433
• Page End: 6439
• Publication Date: 2015-03-07
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c4cp05694a
• Languages: English
• ISSNs: 1463-9076

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj40wc26r" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />The stepwise decomposition of fluorophosphoryl diazide (FP(O)(N₃)₂), <italic>via</italic> nitrene (FP(O)(N₃)N) and the cyclic intermediate (FP(O)N₂), was experimentally and theoretically studied.</p> </abstract>