Remote rearrangement of the metal center in a (η6-C6Me6)Ru(ii) complex1. Issue 24 (25th March 2015)
- Record Type:
- Journal Article
- Title:
- Remote rearrangement of the metal center in a (η6-C6Me6)Ru(ii) complex1. Issue 24 (25th March 2015)
- Main Title:
- Remote rearrangement of the metal center in a (η6-C6Me6)Ru(ii) complex1
- Authors:
- Takano, Koichi
Ikeda, Yousuke
Kodama, Shintaro
Ishii, Youichi - Abstract:
- <abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjbf9x2nm" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Reaction of [(η<sup>6</sup>-C<sub>6</sub>Me<sub>6</sub>)Ru(Ph)(PMe<sub>3</sub>)]<sup>+</sup> with internal alkynes gave rise to the 1, 4-Ru migration to form the <italic>o</italic>-vinylaryl complex, providing the first example of 1, 4-metal migration of a group 8 metal center; in one case further isomerization to an η<sup>3</sup>-allyl complex was observed.</p> </abstract>
- Is Part Of:
- Chemical communications. Volume 51:Issue 24(2015)
- Journal:
- Chemical communications
- Issue:
- Volume 51:Issue 24(2015)
- Issue Display:
- Volume 51, Issue 24 (2015)
- Year:
- 2015
- Volume:
- 51
- Issue:
- 24
- Issue Sort Value:
- 2015-0051-0024-0000
- Page Start:
- 4981
- Page End:
- 4984
- Publication Date:
- 2015-03-25
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c4cc09699a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 4082.xml