Metal-free Lewis acid mediated dehydrocoupling of phosphines and concurrent hydrogenation1. Issue 12 (11th February 2015)
- Record Type:
- Journal Article
- Title:
- Metal-free Lewis acid mediated dehydrocoupling of phosphines and concurrent hydrogenation1. Issue 12 (11th February 2015)
- Main Title:
- Metal-free Lewis acid mediated dehydrocoupling of phosphines and concurrent hydrogenation1
- Authors:
- Dobrovetsky, Roman
Takeuchi, Katsuhiko
Stephan, Douglas W. - Abstract:
- <abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj9nqwnvc" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />The stoichiometric reaction of trityl cation with two equivalents of Ph<sub>2</sub>PH affords the phosphine stabilized phosphenium salt [Ph<sub>2</sub>(H)PPPh<sub>2</sub>][B(C<sub>6</sub>F<sub>5</sub>)<sub>4</sub>] <italic>via</italic> hydride abstraction, while catalytic amounts of B(<italic>p</italic>-HC<sub>6</sub>F<sub>4</sub>)<sub>3</sub> effects catalytic phosphine dehydrocoupling with the liberation of H<sub>2</sub>.</p> </abstract>
- Is Part Of:
- Chemical communications. Volume 51:Issue 12(2015)
- Journal:
- Chemical communications
- Issue:
- Volume 51:Issue 12(2015)
- Issue Display:
- Volume 51, Issue 12 (2015)
- Year:
- 2015
- Volume:
- 51
- Issue:
- 12
- Issue Sort Value:
- 2015-0051-0012-0000
- Page Start:
- 2396
- Page End:
- 2398
- Publication Date:
- 2015-02-11
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c4cc09526j ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 3574.xml