ChemInform Abstract: Solid‐State Crystal‐to‐Crystal Phase Transitions and Reversible Structure—Temperature Behavior of Phosphovanadomolybdic Acid, H5PV2Mo10O40. Issue 13 (March 2015)

• Record Type: Journal Article
• Authors: Barats‐Damatov, Delina; Shimon, Linda J. W.; Feldman, Yishay; Bendikov, Tatyana; Neumann, Ronny
• Is Part Of: ChemInform. Volume 46:Issue 13(2015)
• Page Start: no
• Page End: no
• Publication Date: 2015-03
• Subjects: Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201513008
• Languages: English
• ISSNs: 0931-7597

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The crystal packing and secondary structure of H₅PV₂Mo₁₂O₄₀ (prepared according to the literature) is analyzed by powder XRD and reveals 4 unique structures (36, 14, 8 units of crystal H₂O, the latter in two modifications) and 3 reversible solid phase transitions between 25 and 55 °C depending on the loss of solvated H₂O and concomitant contraction of the cell volume and increase of packing density.</p> </abstract>