Alkyl Halide‐Free Heteroatom Alkylation and Epoxidation Facilitated by a Recyclable Polymer‐Supported Oxidant for the In‐Flow Preparation of Diazo Compounds. Issue 12 (11th February 2015)

Record Type:: Journal Article
Title:: Alkyl Halide‐Free Heteroatom Alkylation and Epoxidation Facilitated by a Recyclable Polymer‐Supported Oxidant for the In‐Flow Preparation of Diazo Compounds. Issue 12 (11th February 2015)
Main Title:: Alkyl Halide‐Free Heteroatom Alkylation and Epoxidation Facilitated by a Recyclable Polymer‐Supported Oxidant for the In‐Flow Preparation of Diazo Compounds
Authors:: Nicolle, Simon M.
Hayes, Christopher J.
Moody, Christopher J.
Abstract:: <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Highly reactive metal carbenes, generated from simple ketones via diazo compounds, including diazo‐amides and ‐phosphonates, using a recyclable reagent in‐flow, are transient but versatile electrophiles for heteroatom alkylation reactions and for epoxide formation. The method produces no organic waste, with the only by‐products being water, KI and nitrogen, without the attendant hazards of isolation of intermediate diazo compounds.</p> </abstract>
Is Part Of:: Chemistry. Volume 21:Issue 12(2015)
Journal:: Chemistry
Issue:: Volume 21:Issue 12(2015)
Issue Display:: Volume 21, Issue 12 (2015)
Year:: 2015
Volume:: 21
Issue:: 12
Issue Sort Value:: 2015-0021-0012-0000
Page Start:: 4576
Page End:: 4579
Publication Date:: 2015-02-11
Subjects:: Chemistry -- Periodicals
540
Journal URLs:: http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3765 ↗
http://onlinelibrary.wiley.com/ ↗
DOI:: 10.1002/chem.201500118 ↗
Languages:: English
ISSNs:: 0947-6539
Deposit Type:: Legaldeposit
View Content:: Available online (eLD content is only available in our Reading Rooms) ↗
Physical Locations:: British Library DSC - 3168.860500
British Library DSC - BLDSS-3PM
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Ingest File:: 4261.xml