Flux crystal growth and structural analysis of two cesium uranium oxides, Cs2.2U5O16 and Cs2U4O13, containing multiple cation–cation interactions. Issue 9 (7th March 2015)

• Record Type: Journal Article
• Authors: Morrison, Gregory; Read, Cory M.; Smith, Mark D.; Loye, Hans-Conrad zur
• Is Part Of: CrystEngComm. Volume 17:Issue 9(2015)
• Page Start: 1968
• Page End: 1974
• Publication Date: 2015-03-07
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c4ce02430c
• Languages: English
• ISSNs: 1466-8033

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj40vgnd0" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Single crystals of fully oxidized Cs₂U₄O₁₃ and partially reduced Cs_2.2U₅O₁₆ were grown from a CsCl flux. Both structures contain multiple cation–cation interactions which arise due to the three dimensional connectivity of their uranium frameworks.</p> </abstract>