Controlling the organization of phosphonium cations relative to p-sulfonatocalix[4]arene anions1. Issue 7 (21st February 2015)

• Record Type: Journal Article
• Authors: Ling, Irene; Sobolev, Alexandre N.; Raston, Colin L.
• Is Part Of: CrystEngComm. Volume 17:Issue 7(2015)
• Page Start: 1526
• Page End: 1530
• Publication Date: 2015-02-21
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c4ce02086c
• Languages: English
• ISSNs: 1466-8033

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj40x79w3" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />A composite material containing supermolecules of 1, 4-bis(triethylammoniomethyl)benzene and <italic>p</italic>-sulfonated calix[4]arene involves preferential binding of the ammonium moieties in the cavities of two geometrically opposed calixarenes with mono-phosphonium cations arranged in the <italic>endo</italic>-orientation with respect to the calixarene bilayers, as a multi-layered structure.</p> </abstract>