Inside Back Cover: Well‐Defined Single‐Site Monohydride Silica‐Supported Zirconium from Azazirconacyclopropane (Chem. Eur. J. 11/2015). Issue 11 (9th March 2015)

• Record Type: Journal Article
• Authors: Hamzaoui, Bilel; Eter, Mohamad El; Abou‐hamad, Edy; Chen, Yin; Pelletier, Jérémie D. A.; Basset, Jean‐Marie
• Is Part Of: Chemistry. Volume 21:Issue 11(2015)
• Page Start: 4467
• Page End: 4467
• Publication Date: 2015-03-09
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201590040
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Monohydride silica‐supported zirconium</bold> The silica‐supported azazirconacyclopropane SiOZr(HNMe₂)(η²‐NMeCH₂)(NMe₂) (<bold>1</bold>) leads exclusively under hydrogenolysis conditions (H₂, 150 °C) to the single‐site monopodal monohydride silica‐supported zirconium species SiOZr(HNMe₂)(NMe₂)₂H (<bold>2</bold>). Reactivity studies by allowing compound <bold>2</bold> to come into contact with ethylene, hydrogen/ethylene, propene, or hydrogen/propene, at a temperature of 200 °C revealed alkene hydrogenation. For more details, see the Full Paper by Jean‐Marie Basset et al. on <ext-link ext-link-type="doi" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">page 4294 ff.</ext-link><boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgj3dv37s5" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>