A Convenient Route to Tetraalkylammonium Perfluoroalkoxides from Hydrofluoroethers1. (22nd January 2015)
- Record Type:
- Journal Article
- Title:
- A Convenient Route to Tetraalkylammonium Perfluoroalkoxides from Hydrofluoroethers1. (22nd January 2015)
- Main Title:
- A Convenient Route to Tetraalkylammonium Perfluoroalkoxides from Hydrofluoroethers1
- Authors:
- Jelier, Benson J.
Howell, Jon L.
Montgomery, Craig D.
Leznoff, Daniel B.
Friesen, Chadron M. - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Hydrofluoroethers are shown to alkylate tertiary amines readily under solvent‐free conditions, affording valuable tetraalkylammonium perfluoroalkoxides bearing α‐fluorines. The reaction of R<sub>F</sub>CF<sub>2</sub>OCH<sub>3</sub> (R<sub>F</sub>=CF<sub>2</sub>CF<sub>3</sub>, CF<sub>2</sub>CF<sub>2</sub>CF<sub>3</sub>, and CF(CF<sub>3</sub>)<sub>2</sub>) with NR<sup>1</sup>R<sup>2</sup>R<sup>3</sup> produces twenty new α‐perfluoroalkoxides, [(CH<sub>3</sub>)NR<sup>1</sup>R<sup>2</sup>R<sup>3</sup>][R<sub>F</sub>CF<sub>2</sub>O] under mild conditions. These α‐perfluoroalkoxides are easy to handle, thermally stable, and can be used for the perfluoroalkoxylation of benzyl bromides.</p> </abstract>
- Is Part Of:
- Angewandte Chemie. Volume 127:Number 10(2015)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 127:Number 10(2015)
- Issue Display:
- Volume 127, Issue 10 (2015)
- Year:
- 2015
- Volume:
- 127
- Issue:
- 10
- Issue Sort Value:
- 2015-0127-0010-0000
- Page Start:
- 2988
- Page End:
- 2992
- Publication Date:
- 2015-01-22
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201410639 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 3538.xml