SrBa2(NH2)6: A New Ternary Amide from Ammonothermal Synthesis1. Issue 2 (25th November 2014)

• Record Type: Journal Article
• Authors: Hertrampf, Jan; Alt, Nicolas S. A.; Schlücker, Eberhard; Niewa, Rainer
• Is Part Of: Zeitschrift für anorganische und allgemeine Chemie. Volume 641:Issue 2(2015)
• Page Start: 234
• Page End: 237
• Publication Date: 2014-11-25
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1002/zaac.201400455
• Languages: English
• ISSNs: 0044-2313

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Single crystals of SrBa₂(NH₂)₆ were obtained from the reaction of barium and strontium metal under ammonothermal conditions at a pressure of 180 MPa and a temperature of 573 K. The crystal structure [<italic>a</italic> = 6.395(2) Å, <italic>b</italic> = 7.195(2) Å, <italic>c</italic> = 10.471(2) Å, <italic>β</italic> = 97.99(2)°, <italic>Z</italic> = 2, <italic>V</italic> = 477.13(2) ų, <italic>P</italic>2₁/<italic>n</italic>] contains Ba in sevenfold and Sr in octahedral coordination by amide ions, similar to the enviroments of these metal ions in the binary amides. Further, IR and Raman data are reported.</p> </abstract>