Stability and structure changes of Na-titanate nanotubes at high temperature and high pressure. Issue 2 (24th April 2014)

• Record Type: Journal Article
• Authors: Xu, Huifang; Li, Chenxiang; He, Duanwei; Jinag, Yingbing
• Is Part Of: Powder diffraction. Volume 29:Issue 2(2014)
• Page Start: 147
• Page End: 150
• Publication Date: 2014-04-24
• Subjects: Powder metallurgy -- Periodicals; Materials -- Analysis -- Periodicals; 620.1127
• DOI: 10.1017/S0885715614000220
• Languages: English
• ISSNs: 0885-7156

Abstract

<abstract abstract-type="normal"> <title> <x content-type="archive" xml:space="preserve">Abstract</x> </title> <p>Stability of Na-titanate-based nanotubes at high temperature and pressure is investigated using X-ray diffraction and energy-dispersive X-ray diffraction (EDXRD). Our results show that the nanotubes can be stable at ~400 °C. Higher temperature annealing of nanotubes result in opening and flattening of the nanotubes, and subsequent structural transformation to Na₂Ti₆O₁₃-based structure via an intermediate phase with Na_0.23TiO₂-like structure. <italic>In situ</italic> EDXRD using diamond anvil cell indicates that the nanotubes collapse at about 15 GPa, and are finally transformed into an amorphous phase at about 30 GPa. The nanotubes kept in an amorphous state were further compressed to 50 GPa according to our <italic>in situ</italic> EDXRD observation. Titanate nanotubes are mechanically stronger than carbon nanotubes under static compression.</p> </abstract>