Carbon‐Dot‐Decorated Nanodiamonds. (13th January 2014)

• Record Type: Journal Article
• Authors: Shenderova, Olga; Hens, Suzanne; Vlasov, Igor; Turner, Stuart; Lu, Ying‐Gang; Van Tendeloo, Gustaaf; Schrand, Amanda; Burikov, Sergey A.; Dolenko, Tatiana A.
• Is Part Of: Particle and particle systems characterization. Volume 31:Number 5(2014:May)
• Page Start: 580
• Page End: 590
• Publication Date: 2014-01-13
• Subjects: Particles -- Periodicals; 620.43
• DOI: 10.1002/ppsc.201300251
• Languages: English
• ISSNs: 0934-0866

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>The synthesis of a new class of fluorescent carbon nanomaterials, carbon‐dot‐decorated nanodiamonds (CDD‐ND), is reported. These CDD‐NDs are produced by specific acid treatment of detonation soot, forming tiny rounded sp² carbon species (carbon dots), 1–2 atomic layers thick and 1–2 nm in size, covalently attached to the surface of the detonation diamond nanoparticles. A combination of nanodiamonds bonded with a graphitic phase as a starting material and the application of graphite intercalated acids for oxidation of the graphitic carbon is necessary for the successful production of CDD‐ND. The CDD‐ND photoluminescence (PL) is stable, 20 times more intense than the intrinsic PL of well‐purified NDs and can be tailored by changing the oxidation process parameters. Carbon‐dot‐decorated DNDs are shown to be excellent probes for bioimaging applications and inexpensive additives for PL nanocomposites.</p> </abstract>