Cooperative Effect of Two Metals: CoPd(OAc)4‐Catalyzed CH Amination and Aziridination. Issue 18 (26th March 2014)

• Record Type: Journal Article
• Authors: Huang, Guan‐Hao; Li, Jian‐Min; Huang, Jing‐Jyun; Lin, Jyun‐Dai; Chuang, Gary Jing
• Is Part Of: Chemistry. Volume 20:Issue 18(2014)
• Page Start: 5240
• Page End: 5243
• Publication Date: 2014-03-26
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201304633
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The first Co/Pd‐cocatalyzed intramolecular CH amination and aziridination reactions were developed. Sulfamate esters were converted to oxathiazinanes by using CoPd(OAc)₄ as catalyst and PhI(OAc)₂ as oxidant. The mutual presence of both Co and Pd is crucial for the catalytic activity. This combination of two metals with simple acetate ligands provides an economical alternative to the Rh‐catalyzed insertion of nitrenoids into CH bonds.</p> </abstract>