Borylation of Unactivated Aryl Chlorides under Mild Conditions by Using Diisopropylaminoborane as a Borylating Reagent. Issue 19 (11th April 2014)

• Record Type: Journal Article
• Authors: Guerrand, Hélène D. S.; Marciasini, Ludovic D.; Jousseaume, Mélissa; Vaultier, Michel; Pucheault, Mathieu
• Is Part Of: Chemistry. Volume 20:Issue 19(2014)
• Page Start: 5573
• Page End: 5579
• Publication Date: 2014-04-11
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201304861
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The synthesis of arylboronic ester derivatives from aryl chlorides by using aryl(amino)boranes is described. Palladium‐catalyzed coupling between aryl chlorides and diisopropylaminoborane leads to the formation of a CB bond under mild conditions. A wide range of functional groups are tolerated, making this method particularly useful for the borylation of functionalized aromatics.</p> </abstract>