A Luminescent Cage‐Like Complex Constructed by Bidentate Pyridine‐Containing Ligand and Silver Nitrate. Issue 1 (26th November 2012)

• Record Type: Journal Article
• Authors: Liu, Ying; Yu, Ying‐Hui; Liu, Yi‐Fu; Hou, Guang‐Feng; Wang, Xiao‐Dan; Wen, Bo; Gao, Jin‐Sheng
• Is Part Of: Zeitschrift für anorganische und allgemeine Chemie. Volume 639:Issue 1(2013)
• Page Start: 193
• Page End: 196
• Publication Date: 2012-11-26
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1002/zaac.201200344
• Languages: English
• ISSNs: 0044-2313

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The cage‐like complex, Ag₄L₄(NO₃)₄ (<bold>1</bold>) [L = 1, 4‐bis(pyridine‐2‐ylmethoxy)benzene] was synthesized by the reaction of the flexible bidentate ligand and silver nitrate. It was characterized by elemental analysis, IR spectroscopy, TG, and single‐crystal X‐ray analysis. Complex <bold>1</bold> is reported as the first cage‐like cluster constructed by four nitrate anions bridging two [2+2] macrocycles. A blue luminescent emission and luminescent enhancement effect are observed in complex <bold>1</bold>.</p> </abstract>