<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The one‐step double Suzuki—Miyaura coupling reaction of 2‐aryl‐1, 1‐dibromo‐1‐alkenes with aryl/heteroarylboronic acids proceeds under ligand‐, additive‐, and inert‐gas‐free conditions using aqueous PEG as solvent.</p> </abstract>