ChemInform Abstract: Effect of pH and Reaction Time on the Structures of Early Lanthanide(III) Borate Perchlorates. Issue 7 (22nd February 2013)

• Record Type: Journal Article
• Authors: Polinski, Matthew J.; Wang, Shuao; Alekseev, Evgeny V.; Cross, Justin N.; Depmeier, Wulf; Albrecht‐Schmitt, Thomas E.
• Is Part Of: ChemInform. Volume 44:Issue 7(2013)
• Page Start: no
• Page End: no
• Publication Date: 2013-02-22
• Subjects: Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201307015
• Languages: English
• ISSNs: 0931-7597

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Reactions of LnCl₃ (Ln: La—Nd, Sm, Eu) with 11 M HClO₄ in molten H₃BO₃ (autoclave, 240 °C, 3, 5, or 7 d) lead to the formation of Ln[B₈O₁₀(OH)₆(H₂O) (ClO₄)]·0.5H₂O (Ln: La—Nd, Sm), Pr[B₈O₁₁(OH)₄(H₂O) (ClO₄)], Ln[B₇O₁₁(OH)(H₂O)₂ (ClO₄)] (Ln: Pr, Nd, Sm, Eu), and Ce[B₈O₁₁(OH)₄(H₂O) (ClO₄)] depending on the lanthanide metal and the reaction time.</p> </abstract>