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ChemInform Abstract: Subtle Impact of Atomic Ratio, Charge and Lewis Basicity on Structure Selection and Stability. The Zint Anion [(La@In2Bi11)(μ‐Bi)2 (La@In2Bi11)]6‐. Issue 6 (20th February 2013)
Record Type:
Journal Article
Title:
ChemInform Abstract: Subtle Impact of Atomic Ratio, Charge and Lewis Basicity on Structure Selection and Stability. The Zint Anion [(La@In2Bi11)(μ‐Bi)2 (La@In2Bi11)]6‐. Issue 6 (20th February 2013)
Main Title:
ChemInform Abstract: Subtle Impact of Atomic Ratio, Charge and Lewis Basicity on Structure Selection and Stability. The Zint Anion [(La@In2Bi11)(μ‐Bi)2 (La@In2Bi11)]6‐.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Black, prismatic crystals of [K([2.2.2]crypt)]<sub>6</sub>{ [La@In<sub>2</sub>Bi<sub>11</sub>](μ‐Bi)<sub>2</sub> [La@In<sub>2</sub>Bi<sub>11</sub>]}·3en·3toluene are synthesized by addition of a suspension of [La(C<sub>5</sub>Me<sub>4</sub>H)<sub>3</sub>] (tris(tetramethylcyclopentadienyl)lanthanum) in toluene to a solution of [K([2.2.2]crypt)]<sub>2</sub>[InBi<sub>3</sub>]·en in en (vigorous stirring, 20 °C, 3 h, 11% yield).</p> </abstract>