This is an interim version of our Electronic Legal Deposit Catalogue-eJournals and eBooks while we continue to recover from a cyber-attack.
ChemInform Abstract: Enantioselective Synthesis of 2, 5‐Dihydrobenzo[b]azepine Derivatives via Iridium‐Catalyzed Asymmetric Allylic Amination with 2‐Allylanilines and Ring‐Closing‐Metathesis Reaction. Issue 2 (9th January 2013)
Record Type:
Journal Article
Title:
ChemInform Abstract: Enantioselective Synthesis of 2, 5‐Dihydrobenzo[b]azepine Derivatives via Iridium‐Catalyzed Asymmetric Allylic Amination with 2‐Allylanilines and Ring‐Closing‐Metathesis Reaction. Issue 2 (9th January 2013)
Main Title:
ChemInform Abstract: Enantioselective Synthesis of 2, 5‐Dihydrobenzo[b]azepine Derivatives via Iridium‐Catalyzed Asymmetric Allylic Amination with 2‐Allylanilines and Ring‐Closing‐Metathesis Reaction.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Asymmetric allylic amination of allylic carbonates (II) and (VIII) with o‐allylanilines (I) provides access towards N‐allylamines as branched isomers (III) and (IX), resp., with high to excellent regio‐ (90:10 ‐ 99:1) and enantioselectivity (up to 99% e.e.).</p> </abstract>