Back Cover: Crystal Structures and Phase‐Transition Dynamics of Cobaltocenium Salts with Bis(perfluoroalkylsulfonyl)amide Anions: Remarkable Odd–Even Effect of the Fluorocarbon Chains in the Anion (Chem. Eur. J. 20/2013). Issue 20 (2nd May 2013)

• Record Type: Journal Article
• Authors: Mochida, Tomoyuki; Funasako, Yusuke; Inagaki, Takashi; Li, Meng‐Jiao; Asahara, Kotaro; Kuwahara, Daisuke
• Is Part Of: Chemistry. Volume 19:Issue 20(2013)
• Page Start: 6508
• Page End: 6508
• Publication Date: 2013-05-02
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201390072
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>A remarkable odd–even effect</bold> in their crystal structures and melting entropies is observed for cobaltocenium salts with bis(perfluoroalkylsulfonyl)amide (C_{<italic>n</italic>}F_{2<italic>n</italic>+1}SO₂)₂N anions (<italic>n</italic>=0–4). In the salts with even <italic>n</italic>, the cations and anions are stacked alternately to form mixed columns, whereas the cations and anions form segregated columns in the salts with odd <italic>n.</italic> For more details on the structures and properties of these compounds see the Full Paper by T. Mochida et al. on <ext-link ext-link-type="doi" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">page 6257 ff.</ext-link><boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1ztc5d33" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>