Back Cover: Encapsulation of Metalloporphyrins in a Self‐Assembled Cubic M8L6 Cage: A New Molecular Flask for Cobalt–Porphyrin‐Catalysed Radical‐Type Reactions (Chem. Eur. J. 31/2013). Issue 31 (19th July 2013)

• Record Type: Journal Article
• Authors: Otte, Matthias; Kuijpers, Petrus F.; Troeppner, Oliver; Ivanović‐Burmazović, Ivana; Reek, Joost N. H.; de Bruin, Bas
• Is Part Of: Chemistry. Volume 19:Issue 31(2013)
• Page Start: 10420
• Page End: 10420
• Publication Date: 2013-07-19
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201390116
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Radicals caged in a cube!</bold> A new, large cubic M₈L₆ host capable of encapsulating a catalytically active metalloradical‐type cobalt–porphyrin catalyst is described by de Bruin and co‐workers in their Full Paper on <ext-link ext-link-type="doi" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">page 10170 ff.</ext-link> The reactions mediated by this system are the first examples of cobalt–porphyrin‐catalyzed radical‐type transformations involving diazo compounds that occur inside a supramolecular cage. The cover is an artistic impression of their work in the typical cubistic style of the Dutch painter Piet Mondriaan.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg2771p1nb" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>