Design and Preparation of Molybdenum–Dinitrogen Complexes with Ferrocenyldiphosphine and Pentamethylcyclopentadienyl Moieties as Auxiliary Ligands. Issue 36 (16th August 2013)

• Record Type: Journal Article
• Authors: Miyazaki, Takamasa; Tanabe, Yoshiaki; Yuki, Masahiro; Miyake, Yoshihiro; Nakajima, Kazunari; Nishibayashi, Yoshiaki
• Is Part Of: Chemistry. Volume 19:Issue 36(2013)
• Page Start: 11874
• Page End: 11877
• Publication Date: 2013-08-16
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201302700
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Fix me!</bold> Molybdenum–dinitrogen complexes containing ferrocenyldiphosphine and pentamethylcyclopentadienyl moieties as auxiliary ligands have been designed, prepared, and characterized (see scheme). The ferrocenyldiphosphine works as a unique ligand to inhibit dissociation of dinitrogen, as well as to make the coordinated molecular dinitrogen reactive toward electrophiles.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg36r4btj8" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>