Colloidal Size Effect and Metal‐Particle Migration in M@MOF/PCP Catalysis1. Issue 41 (17th September 2013)

• Record Type: Journal Article
• Authors: Hermannsdörfer, Justus; Friedrich, Martin; Kempe, Rhett
• Is Part Of: Chemistry. Volume 19:Issue 41(2013)
• Page Start: 13652
• Page End: 13657
• Publication Date: 2013-09-17
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201302809
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Metal–organic framework catalysis</bold>: MIL‐101 crystallites have been synthesized in different sizes and infiltrated with the Pd precursor complex [Pd(C₅H₅)(C₃H₅)]. Reduction of the Pd precursor complex gave rise to Pd nanoparticles inside the cavities of MIL‐101 crystallites. Catalytic studies showed a clear dependence of the catalytic activity on the MIL‐101 crystallite size. Furthermore, Pd‐nanoparticle migration from MIL‐101 crystallite to crystallite was observed under mild conditions (see figure).<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg3j1pq2z3" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>