The Lewis Base Stabilized Parent Arsanylborane H2AsBH2⋅NMe3. Issue 36 (31st July 2013)

• Record Type: Journal Article
• Authors: Marquardt, Christian; Adolf, Ariane; Stauber, Andreas; Bodensteiner, Michael; Virovets, Alexander V.; Timoshkin, Alexey Y.; Scheer, Manfred
• Is Part Of: Chemistry. Volume 19:Issue 36(2013)
• Page Start: 11887
• Page End: 11891
• Publication Date: 2013-07-31
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201302110
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Exclusively hydrogen‐substituted arsanylboranes</bold>: The synthesis of the unprecedented Lewis base stabilized monomeric parent compound of the arsanylborane H₂AsBH₂<bold>⋅</bold>NMe₃ was achieved in a one‐pot reaction in high yield and purity. The analogous phosphanylborane was synthesized in a similar manner. A series of different reactions was performed on H₂AsBH₂<bold>⋅</bold>NMe₃ to show its broad reactivity pattern.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg36r4bwj9" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>