Imidazole–Nitrile or Imidazole–Isonitrile CC Coupling on Rhenium Tricarbonyl Complexes. Issue 39 (3rd September 2013)

• Record Type: Journal Article
• Authors: Viguri, Maialen Espinal; Huertos, Miguel A.; Pérez, Julio; Riera, Lucía
• Is Part Of: Chemistry. Volume 19:Issue 39(2013)
• Page Start: 12974
• Page End: 12977
• Publication Date: 2013-09-03
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201302303
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Ligand activation</bold>: Deprotonation of the nitrile or isonitrile complexes [Re(CO)₃(N‐RIm)₂(L)]⁺ (N‐RIm=N‐alkylimidazole; L=NC<italic>t</italic>Bu, CN<italic>t</italic>Bu) selectively afforded alkylidenamido or iminoacyl derivatives, respectively, in which CC coupling has occurred. Protonation of the latter complex leads to aminocarbene products.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg3hfwgc29" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>