Photopolymerization Reactions Using the Photoinitiated Copper (I)‐Catalyzed Azide‐Alkyne Cycloaddition (CuAAC) Reaction. (11th February 2013)

• Record Type: Journal Article
• Authors: Gong, Tao; Adzima, Brian J.; Baker, Noah H.; Bowman, Christopher N.
• Is Part Of: Advanced materials. Volume 25:Number 14(2013)
• Page Start: 2024
• Page End: 2028
• Publication Date: 2013-02-11
• Subjects: Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.201203815
• Languages: English
• ISSNs: 0935-9648

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>The first bulk photopolymerization of multifunctional alkyne and azide monomers</bold> using the CuAAC reaction is successfully carried out from low molecular weight, nonviscous monomer resins. Compared to other traditional step‐growth bulk photopolymerization, this approach readily provides crosslinked, high glass transition temperature polymers that incorporate triazole linkages throughout the polymer structure with great temporal control. <boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1x46ntxd" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>