Ruthenium‐Catalyzed Direct CH Amidation of Arenes Including Weakly Coordinating Aromatic Ketones. Issue 23 (24th April 2013)

• Record Type: Journal Article
• Authors: Kim, Jiyu; Kim, Jinwoo; Chang, Sukbok
• Is Part Of: Chemistry. Volume 19:Issue 23(2013)
• Page Start: 7328
• Page End: 7333
• Publication Date: 2013-04-24
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201301025
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>CH activation</bold>: The ruthenium‐catalyzed direct sp² CH amidation of arenes by using sulfonyl azides as the amino source is presented (see scheme). A wide range of substrates were readily amidated including arenes bearing weakly coordinating groups. Synthetic utility of the thus obtained products was demonstrated in the preparation of biologically active heterocycles.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg21ckdcw2" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>