A Convenient Palladium‐Catalyzed Carbonylative Synthesis of 2‐Aminbenzoxazinones from 2‐Bromoanilines and Isocyanates. Issue 20 (20th March 2013)

• Record Type: Journal Article
• Authors: Wu, Xiao‐Feng; Sharif, Muhammad; Shoaib, Khurram; Neumann, Helfried; Pews‐Davtyan, Anahit; Langer, Peter; Beller, Matthias
• Is Part Of: Chemistry. Volume 19:Issue 20(2013)
• Page Start: 6230
• Page End: 6233
• Publication Date: 2013-03-20
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201300537
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Mon ami(ne)!</bold> A general and convenient methodology for 2‐aminobenzoxazinone synthesis has been developed (see scheme). Readily available 2‐bromoanilines and isocyanates were used as substrates and various products have been prepared in good yields. Notably, [Mo(CO)₆] as a solid CO source was applied instead of gas.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1ztc53n8" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>