Cobalt‐Catalyzed Electrophilic Amination of Arylzincs with N‐Chloroamines. Issue 20 (22nd March 2013) - Qian, Xin
Abstract Roles reversed: An efficient cobalt‐catalyzed electrophilic amination of arylzinc reagents has been achieved. A variety of functionalized arylzincs and N‐chloroamines were coupled under mild conditions (see scheme). Both secondary and tertiary arylamines were obtained in moderate to excellent yields.