Microwave‐Induced In Situ Synthesis of Zn2GeO4/N‐Doped Graphene Nanocomposites and Their Lithium‐Storage Properties. Issue 19 (11th March 2013)

• Record Type: Journal Article
• Authors: Zou, Feng; Hu, Xianluo; Sun, Yongming; Luo, Wei; Xia, Fangfang; Qie, Long; Jiang, Yan; Huang, Yunhui
• Is Part Of: Chemistry. Volume 19:Issue 19(2013)
• Page Start: 6027
• Page End: 6033
• Publication Date: 2013-03-11
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201204588
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Zn₂GeO₄/N‐doped graphene nanocomposites have been synthesized through a fast microwave‐assisted route on a large scale. The resulting nanohybrids are comprised of Zn₂GeO₄ nanorods that are well‐embedded in N‐doped graphene sheets by in situ reducing and doping. Importantly, the N‐doped graphene sheets serve as elastic networks to disperse and electrically wire together the Zn₂GeO₄ nanorods, thereby effectively relieving the volume‐expansion/contraction and aggregation of the nanoparticles during charge and discharge processes. We demonstrate that an electrode that is made of the as‐formed Zn₂GeO₄/N‐doped graphene nanocomposite exhibits high capacity (1463 mAh g⁻¹ at a current density of 100 mA g⁻¹), good cyclability, and excellent rate capability (531 mAh g⁻¹ at a current density of 3200 mA g⁻¹). Its superior lithium‐storage performance could be related to a synergistic effect of the unique nanostructured hybrid, in which the Zn₂GeO₄ nanorods are well‐stabilized by the high electronic conduction and flexibility of N‐doped graphene sheets. This work offers an effective strategy for the fabrication of functionalized ternary‐oxide‐based composites as high‐performance electrode materials that involve structural conversion and transformation.</p> </abstract>