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Gold‐Catalyzed 1, 2‐Acyloxy Migration/Intramolecular [3+2] 1, 3‐Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium‐Sized‐Ring Ethers and Amines1. (11th August 2014)
Record Type:
Journal Article
Title:
Gold‐Catalyzed 1, 2‐Acyloxy Migration/Intramolecular [3+2] 1, 3‐Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium‐Sized‐Ring Ethers and Amines1. (11th August 2014)
Main Title:
Gold‐Catalyzed 1, 2‐Acyloxy Migration/Intramolecular [3+2] 1, 3‐Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium‐Sized‐Ring Ethers and Amines1
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A highly efficient strategy for the formation of medium‐sized‐ring ethers and amines based on a gold‐catalyzed cascade reaction, involving enynyl ester isomerization and intramolecular [3+2] cyclization, has been developed. Various multisubstituted medium‐sized‐ring unsaturated ethers and amines were obtained through this transformation. This method represents one of the relatively few transition metal catalyzed intramolecular cycloaddition reactions for medium‐sized ring synthesis.</p> </abstract>