This is an interim version of our Electronic Legal Deposit Catalogue-eJournals and eBooks while we continue to recover from a cyber-attack.
ChemInform Abstract: A Photo‐Reagent System of Benzimidazoline and Ru(bpy)3Cl2 to Promote Hexenyl Radical Cyclization and Dowd—Beckwith Ring‐Expansion of α‐Halomethyl‐Substituted Benzocyclic 1‐Alkanones. Issue 36 (9th September 2014)
Record Type:
Journal Article
Title:
ChemInform Abstract: A Photo‐Reagent System of Benzimidazoline and Ru(bpy)3Cl2 to Promote Hexenyl Radical Cyclization and Dowd—Beckwith Ring‐Expansion of α‐Halomethyl‐Substituted Benzocyclic 1‐Alkanones. Issue 36 (9th September 2014)
Main Title:
ChemInform Abstract: A Photo‐Reagent System of Benzimidazoline and Ru(bpy)3Cl2 to Promote Hexenyl Radical Cyclization and Dowd—Beckwith Ring‐Expansion of α‐Halomethyl‐Substituted Benzocyclic 1‐Alkanones.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A benzimidazoline ligand in combination with a Ru‐ or Ir‐complex promotes photoinduced electron‐transfer reactions of α‐halomethyl substituted substrates to form primary alkyl radicals via selective C‐halogen bond cleavage.</p> </abstract>