Back Cover: Oxygenation by Ruthenium Monosubstituted Polyoxotungstates in Aqueous Solution: Experimental and Computational Dissection of a Ru(III)–Ru(V) Catalytic Cycle (Chem. Eur. J. 35/2014). Issue 35 (25th August 2014)

• Record Type: Journal Article
• Authors: Sartorel, Andrea; Miró, Pere; Carraro, Mauro; Berardi, Serena; Bortolini, Olga; Bagno, Alessandro; Bo , Carles; Bonchio, Marcella
• Is Part Of: Chemistry. Volume 20:Issue 35(2014)
• Page Start: 11232
• Page End: 11232
• Publication Date: 2014-08-25
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201490149
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Polyoxometalate ligands</bold> play a key role in facilitating a ruthenium catalyst access to a high‐valent reactive state in aerobic oxidation in water. In their Full Paper on <ext-link ext-link-type="doi" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">page 10932 ff.</ext-link>, C. Bo, M. Bonchio et al. show that the reaction involves novel ruthenium–peroxo and oxene intermediates embedded within a totally inorganic POM environment. This breakthrough perspective is one the central themes of the European COST action entitled Polyoxometalate Chemistry for Molecular Nanoscience (PoCheMoN). The cover art is inspired by the popular fantasy game (Pokémon).<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgh122vjx1p" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>