Efficient cyanation of aryl halide with K4[Fe(CN)6]⋅3H2O catalyzed by a P–O bidentate chelate palladium complex under air. (7th July 2014)

• Record Type: Journal Article
• Authors: Fu, Leiqing; Li, Xiaogang; Zhu, Qiming; Chen, Sanbao; Kang, Yanping; Guo, Mengping
• Is Part Of: Applied organometallic chemistry. Volume 28:Number 9(2014:Sep.)
• Page Start: 699
• Page End: 701
• Publication Date: 2014-07-07
• Subjects: Organometallic chemistry -- Periodicals; Organometallic compounds -- Periodicals; 547.05
• DOI: 10.1002/aoc.3185
• Languages: English
• ISSNs: 0268-2605

Abstract

<abstract abstract-type="main"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <named-content content-type="reactionType" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">Cyanation</named-content> of aryl halide with K₄[Fe(CN)₆]⋅3H₂O has been carried out in the presence of a high‐activity catalyst: an air‐stable P–O bidentate chelate palladium complex. This method is applicable to both activated and deactivated aryl halides, and even a variety of aromatic nitriles are obtained in good yields under aerobic conditions. Copyright © 2014 John Wiley &amp; Sons, Ltd.</p> </abstract>