Selective Reductive Coupling of Nitro Compounds with Aldehydes to Nitrones in H2 Using Carbon‐Supported and ‐Decorated Platinum Nanoparticles1. Issue 35 (9th July 2014)

• Record Type: Journal Article
• Authors: Cisneros, Larisha; Serna, Pedro; Corma, Avelino
• Is Part Of: Angewandte Chemie international edition. Volume 53:Issue 35(2014)
• Page Start: 9306
• Page End: 9310
• Publication Date: 2014-07-09
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201402878
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Nitrones were synthesized in high yields directly from nitro compounds, aldehydes, and H₂ using carbon‐decorated platinum nanoparticles. The high selectivity for nitrone synthesis contrasts that of common supported metal catalysts and corresponds to an increase from roughly 6 to 97 %. The catalytic performance is tuned by precise control of the structure of the active sites and the characteristics of the support.</p> </abstract>