An Experimental and Theoretical Study on Influence of H‐bonding on the Synthesized Azo Derivatives Structures. Issue 1 (2nd November 2012)

• Record Type: Journal Article
• Authors: Amiri, Rahebeh; Haghdadi, Mina; Golshani, Ashkan; Amiri, Maryam Mohamadian; Barikani, Maryam
• Is Part Of: Journal of the Chinese Chemical Society. Volume 60:Issue 1(2013:Jan.)
• Page Start: 45
• Page End: 52
• Publication Date: 2012-11-02
• Subjects: Chemistry -- Periodicals; Electronic journals; 540.5
• DOI: 10.1002/jccs.201200170
• Languages: English
• ISSNs: 0009-4536

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>We have reported a simple and efficient reaction for the synthesis of some new functionalized azo structures which were prepared by electron deficient acetylenic compounds in the presence of triphenylphosphine. The characterization of the synthesized azo compounds has been determined by FTIR, UV‐Vis, ¹H NMR, ¹³C NMR and Mass spectroscopic techniques. The influence of H‐bonding on the products has been shown by different experimental analysis. Also, the regioselectivity of the reaction, tautomerization equilibrium and the stability of products was investigated using DFT calculations at the B3LYP/6‐31G level of theory.</p> </abstract>