ChemInform Abstract: Mild Solvothermal Syntheses and Characterization of Layered Copper Thioantimonates(III) and Thioarsenate(III). Issue 29 (22nd July 2014)

• Record Type: Journal Article
• Authors: Zhang, Chi; Ji, Min; Ji, Shou‐Hua; An, Yong‐Lin
• Is Part Of: ChemInform. Volume 45:Issue 29(2014)
• Page Start: no
• Page End: no
• Publication Date: 2014-07-22
• Subjects: Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201429029
• Languages: English
• ISSNs: 0931-7597

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Rb₂Cu₂Sb₂S₅ (I), Cs₂Cu₂Sb₂S₅ (II), and Rb₈Cu₆As₈S₁₉ (III) are prepared by solvothermal reaction of Cu, Sb (or As₂S₃), S, and Rb₂CO₃ or Cs₂CO₃ in molar ratios of 8:8.2:37.5:5.2 for (I), 8:8.2:50:3.1 for (II), and 6.3:6.1:32.2:5.2 for (III) in diaminopropane and 50 wt.% MeOH/H₂O (autoclave, 160 °C (145 °C for (III)), 5 d, yields of 36%, 32%, and 56% for (I), (II), and (III)).</p> </abstract>