Back Cover: Towards True Carbaporphyrinoids: Synthesis of 21‐Carba‐23‐thiaporphyrin (Angew. Chem. Int. Ed. 19/2014). Issue 19 (15th April 2014)

• Record Type: Journal Article
• Authors: Berlicka, Anna; Dutka, Paweł; Szterenberg, Ludmiła; Latos‐Grażyński, Lechosław
• Is Part Of: Angewandte Chemie international edition. Volume 53:Issue 19(2014)
• Page Start: 4978
• Page End: 4978
• Publication Date: 2014-04-15
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201401138
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>Replacement of a single pyrrole ring by a cyclopentadiene fragment appears to be a compelling strategy for the creation of true carbaporphyrins, which can be regarded as fundamental extensions of the classical porphyrinic motif. In their Communication on <ext-link ext-link-type="doi" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">page 4885 ff., </ext-link> L. Latos‐Grażyński and co‐workers describe the rational approach that allowed incorporation of an unsubstituted cyclopentadiene instead of a pyrrole ring in a heteroporphyrin framework to form 21‐carbathiaporphyrin, the first meso‐substituted true carbaporphyrinoid.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg5nnq10rt" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>