One‐Pot Synthesis of Aliphatic Nitro Compounds by Michael/retro‐Claisen Fragmentation Domino Reaction. Issue 4 (3rd February 2015)

• Record Type: Journal Article
• Authors: Zhang, Wei; Wang, Yanjing; Bai, Cuibing; Wen, Jialong; Wang, Naixing
• Is Part Of: Chinese journal of chemistry. Volume 33:Issue 4(2015:Apr.)
• Page Start: 401
• Page End: 404
• Publication Date: 2015-02-03
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1002/cjoc.201400836
• Languages: English
• ISSNs: 1001-604X

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A novel and concise method for the construction of <italic>γ</italic>‐nitro ketones and 1, 3‐dinitro compounds with chemoselective acyl transfer has been presented under basic conditions via one‐pot reactions. These reactions feature high atom‐ and step‐economic possess, mild condition and simple operation for one‐pot synthesis of aliphatic nitro compounds. This protocol provides the products in good yields. The possible reaction mechanism has also been proposed.</p> </abstract>