An Alternative to the Sandmeyer Approach to Aryl Iodides. Issue 17 (10th March 2015)

• Record Type: Journal Article
• Authors: Hu, Bao; Miller, William H.; Neumann, Kiel D.; Linstad, Ethan J.; DiMagno, Stephen G.
• Is Part Of: Chemistry. Volume 21:Issue 17(2015)
• Page Start: 6394
• Page End: 6398
• Publication Date: 2015-03-10
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201500151
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Iodoarenes are important synthons for a wide range of organic transformations. Here we report a general strategy to prepare singly iodinated electron‐rich aromatic compounds through the intermediacy of diaryliodonium salts. This process, which incorporates a phase separation that greatly simplifies product purification, is an attractive replacement for the Sandmeyer approach to iodoarenes that are otherwise difficult to access.</p> </abstract>