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ChemInform Abstract: A D‐Ribose‐Derived α‐Amino Nitrile as a Versatile Intermediate for the Collective Synthesis of Piperidine‐Type Iminosugar C‐Glycosides. Issue 17 (April 2015)
Record Type:
Journal Article
Title:
ChemInform Abstract: A D‐Ribose‐Derived α‐Amino Nitrile as a Versatile Intermediate for the Collective Synthesis of Piperidine‐Type Iminosugar C‐Glycosides. Issue 17 (April 2015)
Main Title:
ChemInform Abstract: A D‐Ribose‐Derived α‐Amino Nitrile as a Versatile Intermediate for the Collective Synthesis of Piperidine‐Type Iminosugar C‐Glycosides.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Treatment of α‐amino nitrile (I) with AgBF<sub>4</sub> generates an iminium salt intermediate, which is readily functionalized with Grignard reagents to form C‐glycoside products with excellent stereocontrol.</p> </abstract>