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ChemInform Abstract: Trivalent Cation‐Controlled Phase Space of New U(IV) Fluorides, Na3MU6F30 (M: Al3+, Ga3+, Ti3+, V3+, Cr3+, Fe3+): Mild Hydrothermal Synthesis Including an in situ Reduction Step, Structures, Optical, and Magnetic Properties. Issue 17 (April 2015)
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Journal Article
Title:
ChemInform Abstract: Trivalent Cation‐Controlled Phase Space of New U(IV) Fluorides, Na3MU6F30 (M: Al3+, Ga3+, Ti3+, V3+, Cr3+, Fe3+): Mild Hydrothermal Synthesis Including an in situ Reduction Step, Structures, Optical, and Magnetic Properties. Issue 17 (April 2015)
Main Title:
ChemInform Abstract: Trivalent Cation‐Controlled Phase Space of New U(IV) Fluorides, Na3MU6F30 (M: Al3+, Ga3+, Ti3+, V3+, Cr3+, Fe3+): Mild Hydrothermal Synthesis Including an in situ Reduction Step, Structures, Optical, and Magnetic Properties.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Single crystals of the title compounds are hydrothermally synthesized in nearly quantitative yields from aqueous mixtures of UO<sub>2</sub>(OAc)<sub>2</sub>, NaF, HF, and Ti<sub>2</sub>O<sub>3</sub>, or V<sub>2</sub>O<sub>5</sub>, GaF<sub>3</sub>, or FeF<sub>2</sub> for Na<sub>3</sub>MU<sub>6</sub>F<sub>30</sub> (M: Ti, V, Ga, Fe), and from aqueous mixtures of NaUF<sub>5</sub>, HF, and Na<sub>3</sub>AlF<sub>6</sub>, or CrF<sub>3</sub> for Na<sub>3</sub>MU<sub>6</sub>F<sub>30</sub> (M: Al, Cr) (autoclave, 200 °C, 1 d).</p> </abstract>