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ChemInform Abstract: Efficient and Highly Enantioselective Construction of Trifluoromethylated Quaternary Stereogenic Centers via High‐Pressure Mediated Organocatalytic Conjugate Addition of Nitromethane to β, β‐Disubstituted Enones. Issue 17 (April 2015)
Record Type:
Journal Article
Title:
ChemInform Abstract: Efficient and Highly Enantioselective Construction of Trifluoromethylated Quaternary Stereogenic Centers via High‐Pressure Mediated Organocatalytic Conjugate Addition of Nitromethane to β, β‐Disubstituted Enones. Issue 17 (April 2015)
Main Title:
ChemInform Abstract: Efficient and Highly Enantioselective Construction of Trifluoromethylated Quaternary Stereogenic Centers via High‐Pressure Mediated Organocatalytic Conjugate Addition of Nitromethane to β, β‐Disubstituted Enones.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>In comparison to previously developed methods, this high pressure procedure offers several advantages such as a much broader substrate scope, a lower loading of commercially available catalysts, shorter reaction times, and higher enantioselectivities.</p> </abstract>