Synthesis and Characterization of Rhodium(I) Complexes with P–N Donor Ligands and Their Catalytic Application in Transfer Hydrogenation of Carbonyl Group. (23rd March 2015)

• Record Type: Journal Article
• Authors: Borah, Geetika; Sarmah, Podma Pollov; Boruah, Devajani
• Is Part Of: Bulletin of the Korean Chemical Society. Volume 36:Number 4(2015:Apr.)
• Page Start: 1226
• Page End: 1230
• Publication Date: 2015-03-23
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1002/bkcs.10237
• Languages: English
• ISSNs: 0253-2964

Abstract

<abstract abstract-type="graphical" id="bkcs10237-abs-0001"> <title> <x xml:space="preserve">Abstract</x> </title> <p id="bkcs10237-para-0001">Synthesis and characterization of three neutral complexes of Rh(I) with 2‐[2‐(diphenylphosphino) ethyl]pyridine, (PPh₂Etpy) (<bold>a</bold>), 2‐(diphenylphosphino)pyridine (PPh₂py) (<bold>b</bold>), and 3‐(diphenylphosphino)‐1‐propylamine (PPh₂ (CH₂ ) ₃NH₂ ) (<bold>c</bold>) are reported. These complexes exhibit good catalytic activity toward the transfer hydrogenation of carbonyl compounds to the corresponding alcohols with high conversion rate.<boxed-text content-type="graphic" id="bkcs10237-blkfxd-0001" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgjg4qd064" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>