Inverse Chirality Probe in Poly(3‐alkylthiophene) Derivative. Issue 7 (2nd February 2015)

• Record Type: Journal Article
• Authors: Destri, Silvia; Barba, Luisa; Gelmetti, Ilario; Di Bari, Lorenzo; Porzio, William
• Is Part Of: Macromolecular chemistry and physics. Volume 216:Issue 7(2015:Apr.)
• Page Start: 801
• Page End: 807
• Publication Date: 2015-02-02
• Subjects: Polymers -- Periodicals; Polymerization -- Periodicals; Synthetic products -- Periodicals; Macromolecules -- Periodicals; 547.7
• DOI: 10.1002/macp.201400606
• Languages: English
• ISSNs: 1022-1352

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>The preparation and study of a new poly(3‐alkyloxythiophene)—bearing a chiral center—is presented, with particular reference to the evolution of optical activity in passing from solution to solid state. The combination of optical analysis, electronic circular dichroism, and X‐ray diffraction of powders or films supplies strong indications of a possible use of this material as an inverse chiral probe.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgjf8677jd" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>