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ChemInform Abstract: Crystal Structure and Bonding in BaAu5Ga2 and AeAu4+xGa3‐x (Ae: Ba and Eu): Hexagonal Diamond‐Type Au Frameworks and Remarkable Cation/Anion Partitioning in the Ae—Au—Ga Systems. Issue 16 (April 2015)
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Journal Article
Title:
ChemInform Abstract: Crystal Structure and Bonding in BaAu5Ga2 and AeAu4+xGa3‐x (Ae: Ba and Eu): Hexagonal Diamond‐Type Au Frameworks and Remarkable Cation/Anion Partitioning in the Ae—Au—Ga Systems. Issue 16 (April 2015)
Main Title:
ChemInform Abstract: Crystal Structure and Bonding in BaAu5Ga2 and AeAu4+xGa3‐x (Ae: Ba and Eu): Hexagonal Diamond‐Type Au Frameworks and Remarkable Cation/Anion Partitioning in the Ae—Au—Ga Systems.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The new polar intermetallic compounds BaAu<sub>5</sub>Ga<sub>2</sub> (I), BaAu<sub>4.3</sub>Ga<sub>2.7</sub> (II), Ba<sub>1.0</sub>Au<sub>4.5</sub>Ga<sub>2.4</sub> (III), EuAu<sub>4.8</sub>Ga<sub>2.2</sub> (IV), and Eu<sub>1.1</sub>Au<sub>4.4</sub>Ga<sub>2.2</sub> (V) are prepared from the elements (Ta ampules, 500—1000 °C, 3 h—7 d) and characterized by single crystal XRD, magnetic measurements, and TB‐LMTO‐ASA electronic structure calculations.</p> </abstract>