Electron‐rich, Nitrido‐bridged Ruthenium Complexes1. Issue 1 (28th July 2014)

• Record Type: Journal Article
• Authors: Glüer, Arne; Askevold, Bjorn; Schluschaß, Bastian; Heinemann, Frank W.; Schneider, Sven
• Is Part Of: Zeitschrift für anorganische und allgemeine Chemie. Volume 641:Issue 1(2015)
• Page Start: 49
• Page End: 51
• Publication Date: 2014-07-28
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1002/zaac.201400166
• Languages: English
• ISSNs: 0044-2313

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Terminal Ru^IV nitride [RuN{N(CH₂CH₂P<italic>t</italic>Bu₂)₂}] (<bold>1</bold>) and [RuCl{N(CH₂CH₂P<italic>t</italic>Bu₂)₂}] (<bold>2a</bold>) form an equilibrium with bridging nitride [{(<italic>t</italic>Bu₂PCH₂CH₂)₂N}Ru(μ‐N)RuCl{N(CH₂CH₂P<italic>t</italic>Bu₂)₂}] (<bold>3a</bold>). While <bold>3a</bold> could only be spectroscopically characterized yet not isolated, the reaction of the divinylamido chloro complex [RuCl{N(CHCHP<italic>t</italic>Bu₂)₂}] (<bold>2b</bold>) with half an equivalent azide directly gave the analogous bridging nitride [{(<italic>t</italic>Bu₂PCHCH)₂N}Ru(μ‐N)RuCl{N(CHCHP<italic>t</italic>Bu₂)₂}] (<bold>3b</bold>), which was isolated and fully characterized.</p> </abstract>